Proctor & Hughes' chemical hazards of the workplace. 5th ed

CONTENTS Barium (and compounds) 65 Bauxite 66 Benomyl 67 Benz[a]anthracene 68 Benzene 69 Benzidine 73 2,3-Benzofuran 75 Benzoic acid 75 Benzo[a]pyrene 76 Benzotrichloride 78 Benzoyl peroxide 79 Benzyl chloride 80 Beryllium (and compounds) 81 Biphenyl 83 Bismuth telluride 84 Bisphenol A 85 Borates, tetra, sodium salts 87 Boron oxide 88 Boron tribromide 88 Boron trifluoride 89 Bromine 90 Bromine pentafluoride 91 Bromodichloromethane 91 Bromoform 93 1,3-Butadiene 94 n-Butane 96 n-Butyl acetate 98 sec-Butyl acetate 99 tert-Butyl acetate 99 n-Butyl acrylate 100 n-Butyl alcohol 101 sec-Butyl alcohol 102 tert-Butyl alcohol 102 Butylamine 103 tert-Butyl chromate 104 n-Butyl glycidyl ether 105 n-Butyl mercaptan 105 o-sec-Butylphenol 106 p-tert-Butyl toluene 107 Acetaldehyde 13 Acetamide 14 Acetic acid 15 Acetic anhydride 16 Acetone 17 Acetonitrile 19 2-Acetylaminofluorene 20 Acetylene tetrabromide 22 Acrolein 22 Acrylamide 24 Acrylic acid 27 Acrylonitrile 28 Aldrin 30 Allyl alcohol 32 Allyl chloride 32 Allyl glycidyl ether 34 Allyl propyl disulfide 35 Aluminum 36 Aluminum oxides 38 4-Aminodiphenyl 40 p-Aminophenol 41 2-Aminopyridine 42 Amitrole 43 Ammonia 45 Ammonium chloride fume 46 Ammonium perfluorooctanoate 46 Ammonium sulfamate 48 n-Amyl acetate 48 sec-Amyl acetate 49 Aniline 50 Anisidine 52 Antimony (and compounds) 52 ANTU 54 Arsenic (and compounds) 55 Arsine 58 Asbestos 59 Asphalt fumes 61 Atrazine 63 Azinphos-methyl 64 v Cadmium (and compounds) 108 Calcium carbonate 110 Calcium cyanamide 111 Calcium hydroxide 111 Calcium oxide 112 Calcium silicate 113 Calcium sulfate 114 Camphor 114 Caprolactam 115 Carbaryl 116 Carbon black 118 Carbon dioxide 120 Carbon disulfide 121 Carbon monoxide 123 Carbon tetrabromide 126 Carbon tetrachloride 126 Catechol 129 Cellulose (and compounds) 130 Cesium hydroxide 131 Chlordane 131 Chlordecone 133 Chlorinated dibenzo-p-dioxins 134 Chlorinated diphenyl oxide 137 Chlorine 138 Chlorine dioxide 140 Chlorine trifluoride 142 Chloroacetaldehyde 142 Chloroacetone 143 a-Chloroacetophenone 144 Chloroacetyl chloride 145 Chlorobenzene 146 o-Chlorobenzylidene malononitrile 147 Chlorobromomethane 149 p-Chloro-m-cresol 150 Chlorodibromomethane 150 Chlorodifluoromethane 152 Chlorodiphenyl, 42% chlorine 153 Chlorodiphenyl, 54% chlorine 156 Chloroform 158 bis(Chloromethyl)ether 160 Chloromethyl methyl ether 162 1-Chloro-1-nitropropane 163 Chloropentafluoroethane 164 Chloropicrin 165 b-Chloroprene 166 o-Chlorostyrene 168 Chlorothalonil 168 o-Chlorotoluene 169 Chlorpyrifos 170 Chromium (metal and inorganic compounds, as Cr) 172 Chromyl chloride 175 Chrysene 176 Coal dust 177 Coal tar pitch volatiles 178 Cobalt 180 Cobalt hydrocarbonyl 182 Copper (dust and fume) 183 Cotton dust, raw 184 Cresol (all isomers) 186 Crotonaldehyde 187 Cumene 188 Cyanamide 189 Cyanides 190 Cyanogen 191 Cyanogen chloride 193 Cyclohexane 193 Cyclohexanol 195 Cyclohexanone 195 Cyclohexene 197 Cycloheximide 197 Cyclohexylamine 198 Cyclopentadiene 199 Cyclopentane 200 Cymene 201 DDT 202 Decaborane 203 Decalin 204 Demeton 206 Diacetone alcohol 207 2,4-Diaminotoluene 208 Diazomethane 209 Dibenz[a,h]anthracene 210 Diborane 211 1,2-Dibromo-3-chloropropane 212 2-N-Dibutylaminoethanol 214 2,6-Di-tert-butyl-p-cresol 215 Dibutyl phenyl phosphate 216 Dibutyl phosphate 217 Dibutyl phthalate 217 Dichloroacetylene 219 o-Dichlorobenzene 220 p-Dichlorobenzene 221 3,3¢-Dichlorobenzidine 223 Dichlorodifluoromethane 225 1,3-Dichloro-5,5-dimethylhydantoin 226 1,1-Dichloroethane 227 1,2-Dichloroethylene 228 vi CONTENTS Dichloroethyl ether 229 Dichlorofluoromethane 230 1,1-Dichloro-1-nitroethane 231 2,4-Dichlorophenol 231 2,4-Dichlorophenoxyacetic acid 233 1,3-Dichloropropene 235 2,2-Dichloropropionic acid 237 Dichlorotetrafluoroethane 238 Dichlorvos 239 Dicyclopentadiene 241 Dicyclopentadienyl iron 242 Dieldrin 243 Diepoxybutane 244 Diethanolamine 245 Diethylamine 247 2-Diethylaminoethanol 248 Diethylene triamine 249 Diethylhexyl adipate 250 Di(2-ethylhexyl) phthalate 251 Diethyl ketone 253 Diethyl phthalate 253 Diethyl sulfate 254 Difluorodibromomethane 255 Diglycidyl ether 256 Diisobutyl ketone 257 Diisopropylamine 258 Dimethoxyethyl phthalate 258 Dimethylacetamide 259 Dimethylamine 261 4-Dimethylaminoazobenzene 262 N,N-Dimethylaniline 263 Dimethyl carbamoyl chloride 264 Dimethylformamide 265 1,1-Dimethylhydrazine 267 Dimethyl hydrogen phosphite 268 Dimethyl methylphosphonate 270 2,4-Dimethylphenol 271 Dimethyl phthalate 272 Dimethyl sulfate 273 Dinitrobenzene (all isomers) 275 Dinitro-o-cresol 277 2,4-Dinitrophenol 278 Dinitrotoluene (all isomers) 279 Dioxane 281 Diphenylamine 283 1,2-Diphenylhydrazine 284 Dipropylene glycol methyl ether 285 Dipropyl ketone 285 Diquat 286 Disulfiram 287 Disulfoton 288 Divinyl benzene 289 Endosulfan 290 Endrin 291 Enflurane 293 Epichlorohydrin 294 EPN 296 1,2-Epoxybutane 297 Epoxy resins 298 Ethane 301 Ethanolamine 302 2-Ethoxyethanol 303 2-Ethoxyethyl acetate 304 Ethyl acetate 306 Ethyl acrylate 307 Ethyl alcohol 308 Ethylamine 310 Ethyl amyl ketone 310 Ethyl benzene 311 Ethyl bromide 312 Ethyl butyl ketone 314 Ethyl chloride 314 Ethylene 316 Ethylene chlorohydrin 317 Ethylenediamine 318 Ethylene dibromide 319 Ethylene dichloride 321 Ethylene glycol 323 Ethylene glycol dinitrate 325 Ethylene glycol monobutyl ether 326 Ethylene oxide 328 Ethylene thiourea 330 Ethylenimine 332 Ethyl ether 333 Ethyl formate 334 2-Ethylhexyl acrylate 334 Ethylidene norbornene 335 Ethyl mercaptan 336 N-Ethylmorpholine 337 Ethyl silicate 338 Fenthion 338 Ferbam 340 Ferrovanadium dust 341 Fibrous glass/glasswool 342 Fluoranthene 344 Fluorides 345 Fluorine 347 Formaldehyde 347 CONTENTS vii Formic acid 351 Fuel oils 352 Furfural 353 Furfuryl alcohol 354 Gasoline 356 Germanium tetrahydride 358 Glutaraldehyde 358 Glycidol 360 Graphite (natural) 361 Graphite (synthetic) 362 Hafnium (and compounds) 363 Halothane 364 Helium 366 Heptachlor 366 Heptachlor epoxide 367 n-Heptane 368 Hexachlorobenzene 369 Hexachlorobutadiene 371 Hexachlorocyclopentadiene 373 Hexachloroethane 374 Hexachloronaphthalene 375 Hexafluoroacetone 376 Hexamethylene diisocyanate 378 Hexamethyl phosphoramide 379 n-Hexane 380 sec-Hexyl acetate 382 Hexylene glycol 382 HMX 383 Hydrazine 384 Hydrogenated terphenyls 386 Hydrogen bromide 386 Hydrogen chloride 387 Hydrogen cyanide 389 Hydrogen fluoride 390 Hydrogen peroxide (90%) 392 Hydrogen selenide 393 Hydrogen sulfide 394 Hydroquinone 395 Hydroxylamine (and salts) 397 2-Hydroxypropyl acrylate 399 Indene 399 Indenol(1,2,3-cd)pyrene 400 Indium (and compounds) 400 Iodine 402 Iodoform 403 Iron oxide fume 404 Iron pentacarbonyl 405 Isoamyl acetate 405 Isoamyl alcohol 406 Isobutane 407 Isobutyl acetate 408 Isobutyl alcohol 408 Isooctyl alcohol 409 Isophorone 410 Isophorone diisocyanate 411 2-Isopropoxyethanol 412 Isopropyl acetate 412 Isopropyl alcohol 413 Isopropylamine 415 N-isopropylaniline 415 Isopropyl ether 417 Isopropyl glycidyl ether 417 Jet fuels 418 Ketene 420 Lead (inorganic compounds) 420 Lead arsenate 423 Lead chromate 424 Lindane 426 Liquefied petroleum gas 427 Lithium hydride 428 Magnesite 429 Magnesium oxide fume 429 Malathion 430 Maleic anhydride 432 Manganese (and compounds) 433 Manganese cyclopentadienyl tricarbonyl 435 Manganese tetroxide 436 Mercury 436 Mercury (alkyl compounds) 438 Mesityl oxide 440 Methacrylic acid 441 Methane 442 Methomyl 443 Methoxychlor 444 2-Methoxyethanol 445 2-Methoxyethyl acetate 447 4-Methoxyphenol 448 Methyl acetate 449 Methyl acetylene 450 Methyl acrylate 450 Methylacrylonitrile 451 Methylal 453 Methyl alcohol 453 Methylamine 455 Methyl n-amyl ketone 455 N-methyl aniline 456 Methyl bromide 457 Methyl butyl ketone 460 Methyl chloride 462 Methyl 2-cyanoacrylate 463 viii CONTENTS Methylcyclohexane 464 Methylcyclohexanol 465 o-Methylcyclohexanone 466 2-Methylcyclopentadienyl manganese tricarbonyl 466 4,4¢-Methylene bis(2-chloroaniline) 467 Methylene bis-(4-hexylisocyanate) 469 Methylene bisphenyl isocyanate 470 Methylene chloride 471 4,4¢-Methylene dianiline 474 Methyl ethyl ketone 476 Methyl ethyl ketone peroxide 478 Methyl formate 479 Methyl hydrazine 480 Methyl iodide 481 Methyl isoamyl ketone 483 Methyl isobutyl carbinol 483 Methyl isobutyl ketone 484 Methyl isocyanate 485 Methyl isopropyl ketone 486 Methyl mercaptan 487 Methyl methacrylate 488 Methyl parathion 490 Methyl propyl ketone 492 N-methyl-2-pyrrolidone 493 Methyl silicate 494 a-Methyl styrene 495 Mevinphos 496 Mica 497 Molybdenum (and compounds) 498 Morpholine 500 Mustard gas 501 Naled 503 Naphtha, coal tar 505 Naphthalene 506 b-Naphthylamine 507 Nickel (and inorganic compounds) 508 Nickel carbonyl 511 Nicotine 512 Nitric acid 513 Nitric oxide 514 p-Nitroaniline 515 Nitrobenzene 516 p-Nitrobiphenyl 518 o-Nitrochlorobenzene 519 p-Nitrochlorobenzene 520 Nitroethane 522 Nitrogen dioxide 523 Nitrogen mustards (blister agents) 525 Nitrogen trifluoride 526 Nitroglycerin 527 Nitromethane 529 1-Nitropropane 530 2-Nitropropane 531 N-nitrosodimethylamine 532 N-nitrosodiphenylamine 534 N-nitrosodi-n-propylamine 535 N-nitrosomorpholine 536 Nitrotoluene 537 Nitrous oxide 538 Nonane 540 Nonylphenol 541 Nuisance particulates 542 Octachloronaphthalene 543 Octane 544 Oil mist (mineral) 544 Osmium tetroxide 546 Oxalic acid 546 Oxygen difluoride 547 Ozone 548 Paraquat 550 Parathion 552 Particulate matter 554 Pentaborane 555 Pentachloroethane 556 Pentachloronaphthalene 558 Pentachlorophenol 559 Pentaerythritol 561 Pentane 562 2,4-Pentanedione 563 Perchloroethylene 564 Perchloromethyl mercaptan 567 Perchloryl fluoride 567 Phenol 568 p-Phenylenediamine 570 2-Phenylethanol 571 Phenyl ether 572 Phenyl glycidyl ether 573 Phenylhydrazine 574 Phenyl mercaptan 575 N-Phenyl-b-naphthylamine 576 Phenylphosphine 578 Phosgene 579 Phosphine 580 Phosphoric acid 581 Phosphorus (yellow) 582 Phosphorus oxychloride 584 Phosphorus pentachloride 584 Phosphorus pentasulfide 585 Phosphorus trichloride 585 CONTENTS ix Phthalic anhydride 586 m-Phthalodinitrile 587 Picric acid 588 Pindone 589 Piperazine dihydrochloride 589 Platinum (and soluble salts) 590 Polybrominated biphenyls 591 Polytetrafluoroethylene decomposition products 593 Portland cement 594 Potassium hydroxide 596 Propane 596 Propane sultone 597 Propargyl alcohol 598 Propene 599 b-Propiolactone 600 Propionic acid 601 n-Propyl acetate 602 n-Propyl alcohol 603 Propylene dichloride 604 Propylene glycol dinitrate 605 Propylene glycol monomethyl ether 607 Propyleneimine 608 Propylene oxide 609 n-Propyl nitrate 611 Pyrethrum 612 Pyridine 613 Quinone 614 Radon 615 RDX 616 Resorcinol 617 Rhodium (and compounds) 618 Ronnel 620 Rotenone 620 Rubber, natural latex 622 Selenium (and compounds) 623 Selenium hexafluoride 625 Silica, amorphous—diatomaceous earth 625 Silica, amorphous—fume 626 Silica, crystalline—quartz 628 Silicon 630 Silicon carbide 631 Silicon tetrahydride 632 Silver (and compounds) 632 Soapstone 634 Sodium fluoroacetate 634 Sodium hydroxide 636 Sodium metabisulfite 637 Stibine 638 Stoddard solvent 638 Strychnine 639 Styrene, monomer 640 Styrene oxide 642 Sulfolane 643 Sulfur dioxide 644 Sulfur hexafluoride 645 Sulfur monochloride 646 Sulfur pentafluoride 647 Sulfur tetrafluoride 647 Sulfuric acid 648 Sulfuryl fluoride 650 Talc (nonasbestos form) 651 Tantalum 654 Tellurium 654 Tellurium hexafluoride 655 Terphenyls 656 1,1,2,2-Tetrachloro-1,2-difluoroethane 657 1,1,2,2-Tetrachloroethane 657 Tetrachloronaphthalene 659 Tetraethyl lead 659 Tetraethyl pyrophosphate 661 Tetrahydrofuran 662 Tetralin 664 Tetramethyl lead 665 Tetramethyl succinonitrile 666 Tetranitromethane 666 Tetrasodium pyrophosphate 667 Tetryl 668 Thallium 669 Thiazoles—rubber components 671 Thioacetamide 672 4,4¢-Thiobis(6-tert-butyl-m-cresol) 672 Thioglycolic acid 673 Thionyl chloride 674 Thiram 675 Tin (inorganic compounds) 677 Tin (organic compounds) 678 Titanium dioxide 679 Toluene 681 Toluene-2,4-diisocyanate 683 Toluidine 686 Toxaphene 687 Tributyl phosphate 689 Trichloroacetic acid 690 1,2,4-Trichlorobenzene 692 1,1,1-Trichloroethane 692 1,1,2-Trichloroethane 694 Trichloroethylene 696 Trichlorofluoromethane 698 Trichloronaphthalene 699 x CONTENTS 2,4,6-Trichlorophenol 700 2,4,5-Trichlorophenoxyacetic acid 701 1,2,3-Trichloropropane 703 1,1,2-Trichloro-1,2,2-trifluoroethane 704 Triethanolamine 706 Triethylamine 707 Triethylene tetramine 708 Trifluorobromomethane 709 Trimellitic anhydride 710 Trimethylamine 712 Trimethyl benzene 712 Trimethyl phosphite 713 2,4,6-Trinitrotoluene 714 Triorthocresyl phosphate 716 Triphenyl amine 717 Triphenyl phosphate 718 Triphenyl phosphite 719 Tungsten (and compounds) 720 Turpentine 721 Uranium 722 Used mineral-based crankcase oil 724 n-Valeraldehyde 726 Vanadium pentoxide 726 Vinyl acetate 728 Vinyl bromide 730 Vinyl chloride 731 4-Vinylcyclohexene 733 Vinyl cyclohexene dioxide 734 Vinylidene chloride 736 Vinyltoluene 738 VM&P naphtha 739 Warfarin 740 Wood dust 741 Xylene 744 Xylidine (mixed isomers) 746 Yttrium 747 Zinc chloride fume 748 Zinc dithiocarbamates—rubber components 749 Zinc oxide 750 Zirconium compounds 751 CONTENTS xi III CAS Number Index 753 IV Index of Compounds and Synonyms 761